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  • allylboronic acid pinacol ester, 98+%, thermo scientific chemicals
allylboronic acid pinacol ester, 98+%, thermo scientific chemicals

allylboronic acid pinacol ester, 98+%, thermo scientific chemicals

Density :

0.89

Boiling Point :

50°C to 53°C (5 mmHg)

Flash Point :

46°C (140°F)

Refractive Index :

1.427

Quantity :

5 g

UN Number :

UN3272

Beilstein :

4244068

Solubility Information :

Not miscible or difficult to mix in water.

Description :

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

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